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a detailed description of polymer synthesis is given within the electronic supplementary material s (esm, section s1). first, a paa macromolecular chain transfer agent (macro-cta) was prepared by aqueous raft solution polymerisation of aa (see fig. 1 a), which was subsequently chain-extended with a n-butyl acrylate (nba) chain via aqueous raft emulsion polymerisation.

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